BIBO Bismuth Borate

BIBO Bismuth Borate (BiB306) is a newly developed nonlinear optical crystal with a large effective nonlinear optical coefficient, high damage threshold and no moisture solution.

Its nonlinear coefficient was 3.5-4 times higher than LBO and 1.5-2 times higher than BBO. It can efficiently multiply the frequency by 946nm and produce a blue laser at 473nm.


Product Description

BIBO Bismuth Borate (BiB306) is a newly developed nonlinear optical crystal with a large effective nonlinear optical coefficient, high damage threshold and no moisture solution.

Its nonlinear coefficient was 3.5-4 times higher than LBO and 1.5-2 times higher than BBO. It can efficiently multiply the frequency by 946nm and produce a blue laser at 473nm.


Main Features

light transmittance range: 286-2,500 nm

Large effective nonlinear optical coefficient 

High injury threshold

Not easy to tide solution,

Stable physical and chemical performance


Material Properties

Crystal structureorthorhombic system
Crystal lattice parametersa=12.532Å, b=6.71Å, c=10.864Å
Melting point1090℃
Moh's hardness4.5
Density3.85g/cm³
Thermal conductivity10W/(m·K)
Thermal expansion   coefficienta:4.4×10-6/K, b:3.5×10-6/K, c:9.3×10-6/K
Transmissivity>95%(1064nm)
Optical homogeneity<0.1%
Temperature stability<10-5/K
Nonlinear optical coefficient (pm / V)d31=8.8, d32=3.5, d33=13.8
Thermo-optical coeffecientdn/dT=10-5/K
Refractive indexno=2.155, ne=2.220(@1064nm)
Nonlinear coefficient (pm / V)3.5(SHG), 1.8(THG)
Effective frequency doubling coefficient (SHG, THG)1.7(SHG),   0.9(THG)
Walking angle (mrad·cm)32(type I), 42(type II)
Receiving angle (mrad·cm)22.5(type I), 29.5(type II)
Phase Matching Range (℃m)400~1300(SHG), 900~2600(THG)
Temperature acceptance (℃)55
Damage threshold (GW/cm2)~2.5(SHG), ~0.6(THG)


Product Parameters

Dimensional tolerance(W±0.1mm)x(H±0.1mm)x(L+0.5mm/-0.1mm)   (L≥2.5mm)(W±0.1mm)x(H±0.1mm)x(L+0.1mm/-0.1mm)   (L<2.5mm)
Angular tolerance△θ≤±0.25°,△φ≤±0.25°
Parallelism<20″
Verticality<5′
Optical aperture≥90%
Surface finish10-5(MIL-0-13830A)
Flatness<λ/8 @633nm
Wavefront distortion<λ/8 @633nm
Optical   aperture [GW / cm2]>0.3 @1064nm, TEM00, 10ns, 10H z


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